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Solvent effect as the result of frontier molecular orbital interaction. VII. The retro-diels-alder reaction.

✍ Scribed by G. Desimoni; G. Faita; D. Pasini; P.P. Righetti


Book ID
108372071
Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
451 KB
Volume
48
Category
Article
ISSN
0040-4020

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Solvent effect as the result of frontier
✍ G. Desimoni; G. Faita; P.P. Righetti πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 French βš– 613 KB

The solvent effect of the Duels-Alder (DA ) reacnons of N-(2',4'-&chloro-6'-oxo-2',4'-cyclohextien-1'-yhdene)-4-nltrobenzanude (1) was kmetlcally mvestlgated 1. wth 2,3-dlmethylbut @MB), behaves mamly as heterdenophlle whereas, with ethyl vmyl ether (EVE), reacts as hetetiene The mechanism of salvat