Trimethylgermylation and trimethylsilylation of N,N-dialkylacetamides and application of their anions to the Peterson-type reaction
โ Scribed by Shin'ichi Urayama; Sumie Inoue; Yoshiro Sato
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 432 KB
- Volume
- 354
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
trans-Z-NN-dialkylacetamide-1,3-dith 2 have been obtained in high d.e. (>9!kl) and e.e. (up to 94%. >98% after crystallization) by enantioselective oxidation [Ti(i-PrOId. (+)-DET, r-BuOOH]. The aldol-type addition of the magnesium enolate of the N,Ndiethyl derivative (-)-2b to Lso-butyraldehyde affo
The Reaction of Nitramines and Their N-Trimethylsilyl Derivatives with N,N-Bis(trimethylsilyloxy)enamines. -Trimethylsilylated alkylnitramine (I) reacts with N,N-bis(trimethylsilyloxy)aminopropene (II) as N-centered nucleophile to afford selectively the trimethylsilylated oxime (III) which on hydro