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Trimethylgallium based phosphinogallanes. Synthesis and molecular structure of [Me2Ga-P(SiMe3)2]2

✍ Scribed by Mary D.B. Dillingham; Jaye A. Bums; Jameica Byers-Hill; Kevin D. Gripper; William T. Pennington; Gregory H. Robinson


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
333 KB
Volume
216
Category
Article
ISSN
0020-1693

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Synthesis and purification of trimethylg
✍ Kazimierz B. Starowieyski; Andrzej Chwojnowski; Krzysztof Jankowski; Janusz Lewi πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 79 KB πŸ‘ 1 views

Trimethylgallium was obtained from a 3:1 molar mixture of Me 2 AlCl (1) and GaCl 3 (2) only in the presence of NaCl. The mechanism of the reaction was traced. It is postulated that the gallium-aluminium dimers Cl n Me 2Γ€n AlCl 2 GaCl m Me 2Γ€m (m and n = 0, 1 or 2), formed in consecutive alkylation s