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Synthesis and Dynamic Behavior of the Dimeric, Monocyclic Barium Bis[bis(isopropyldimethylsilyl)phosphanide] – Molecular Structures of P(SiMe2Ph)3, of Monomeric (thf)4Ba[P(SiMe2iPr)2]2 and of the Dimer {(thf)2Ba[P(SiMe2iPr]2]2}2

✍ Scribed by Westerhausen, Matthias ;Lang, Gerhard ;Schwarz, Wolfgang


Publisher
Wiley (John Wiley & Sons)
Year
1996
Tongue
English
Weight
555 KB
Volume
129
Category
Article
ISSN
0009-2940

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## Abstract [LiN(SiMe~3~)Ar]~2~ (1, Ar = 2,6‐__i__Pr~2~C~6~H~3~) is prepared by the reaction of HN(SiMe~3~)Ar with __n__BuLi in __n__‐hexane. This compound with an unusual structure contains a four‐membered [LiN]~2~ heterocycle with two solvent‐free two‐coordinate Li centers. Its molecular structur

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