We recently reported the first examples of conjugate additions of alkyl sulphoxides to unsaturated esters,\* These reactions proceed with good selectivity and provide a promising new method for carrying out
✦ LIBER ✦
Trimethylaluminum promoted conjugate additions of dimethylphosphite to α,β-unsaturated esters and ketones
✍ Scribed by Kenneth Green
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- French
- Weight
- 200 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The effective conjugate addition of a dimethyl phosphonate moiety to a&unsaturated esters and kefones is described. This addition is promoted specifically by trimethylaluminum and does not occur with other Lewis acids which have been examined to date.
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