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Stereoselective conjugate additions of sulphoxide stabilised carbanions to α,β-unsaturated esters

✍ Scribed by M. Casey; A.C. Manage; L. Nezhat


Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
266 KB
Volume
29
Category
Article
ISSN
0040-4039

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✦ Synopsis


Summaqv: The reaction of Iithiated a&l t-butyl sulphoxides with a&unsaturated esters gives conjugate addition products in good yield, with high stereoselectivity.

Asymmetric conjugate additions to a&unsaturated carbonyl compounds have been the subject of (


📜 SIMILAR VOLUMES


Stereoselective conjugate additions of b
✍ Mike Casey; Ajith C. Manage; Ray S. Gairns 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 281 KB

We recently reported the first examples of conjugate additions of alkyl sulphoxides to unsaturated esters,\* These reactions proceed with good selectivity and provide a promising new method for carrying out