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Trifluoromethylthiolation of Trimethylsilyl Enol Ethers

โœ Scribed by Munavalli, S.; Rohrbaugh, D. K.; Rossman, D. I.; Wagner, W. G.; Durst, H. D.


Book ID
118068320
Publisher
Taylor and Francis Group
Year
2002
Tongue
English
Weight
147 KB
Volume
177
Category
Article
ISSN
1042-6507

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Site-specific reactions of trimethylsilyl enolates and trimethylsilyldienolates are described. Recently some reactions of the Eschenmoser salt, ,J', with enolates2'3'4, Grignard5a and lithium5b reagents were described. This methodology was used to some advantage in a synthesis of vernolepin.6 A more