Regiospecific synthesis of trimethylsilyl enol ethers via silatropic rearrangements
β Scribed by Coates, Robert M.; Sandefur, L. O.; Smillie, R. D.
- Book ID
- 126833947
- Publisher
- American Chemical Society
- Year
- 1975
- Tongue
- English
- Weight
- 377 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The reductive dehydration of ketones to form olefins has been accomplished in a variety of ways with generally only moderate success. 3 Among the more recent and better ways to make this conversion are those involving hydroboration
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Claisen rearrangement of ally1 vinyl ethers is an important general method of carboncarbon bond formation for synthesis of y,b-unsaturated aldehydes and ketones. 1 Syntheses of y,b-unsaturated esters and amides are similarly achieved by rearrangements of 2-alkoxy and 2amino-3-oxa-1,5-hexadienes.