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Trifluoromethylfluorosulfane and 1,2-Bis(trifluoromethyl)disulfane 1,1′-Difluoride

✍ Scribed by Prof. Dr. F. Seel; Chem.-Ing. W. Gombler


Publisher
John Wiley and Sons
Year
1969
Tongue
English
Weight
219 KB
Volume
8
Category
Article
ISSN
0044-8249

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1,2-Bis(trifluoromethyl)ethene-1,2-dicar
✍ Gonzalo Urrutia-Desmaison; Rolf Huisgen; Heinrich Nöth 📂 Article 📅 2012 🏛 John Wiley and Sons 🌐 German ⚖ 319 KB

## Abstract The title compound (short version: BTE) occurs in (__E__)‐ and (__Z__)‐isomers (both with b.p. of __ca.__ 100°) which equilibrate with nucleophilic catalysts. Both undergo (2+2) cycloadditions with methyl vinyl ether at 25°. Three stereogenic centers in the cyclobutanes led to four __ra