Bis(trifluoromethyl)disulfane Oxide CF3S(O)SCF3
β Scribed by Dr. Willy Gombler
- Publisher
- John Wiley and Sons
- Year
- 1977
- Tongue
- English
- Weight
- 208 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
Earlier arguments concerning D(CF302-CF3) and D(CF3-02) are shown to be probably wrong. New values of 86 and 49 kcal/mol, respectively, are derived. C-0 bond strengths are compared between CF3-and CH3-containing compounds. This relation is of value only if D,(Oz) is independent of X. This is equival
## Abstract Thermal decomposition of bis(trifluoromethyl) peroxydicarbonate has been studied. The mechanism of decomposition is a simple bond fission, homogeneous firstβorder process when the reaction is carried out in the presence of inert gases such as N~2~ or CO. An activation energy of 28.5 kca
The thermal addition of CF,0sCF3(T 1 to CF2CCl2(E) has been investigated between 49.6 and 69.5"C. The initial pressure of CFJ03CF3 was varied between 7 and 240 torr and that of CF2CC12 between 4 and 600 torr. Four products of formula CF30(E),00CF3, wherej = 1 + 4 are formed. The sum of the products