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Bis(trifluoromethyl)disulfane Oxide CF3S(O)SCF3

✍ Scribed by Dr. Willy Gombler


Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
208 KB
Volume
16
Category
Article
ISSN
0044-8249

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πŸ“œ SIMILAR VOLUMES


S-Trifluoromethyl Esters of Thiocarboxyl
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## Abstract For Abstract see ChemInform Abstract in Full Text.

A reexamination of the pyrolysis of bis
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Earlier arguments concerning D(CF302-CF3) and D(CF3-02) are shown to be probably wrong. New values of 86 and 49 kcal/mol, respectively, are derived. C-0 bond strengths are compared between CF3-and CH3-containing compounds. This relation is of value only if D,(Oz) is independent of X. This is equival

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## Abstract Thermal decomposition of bis(trifluoromethyl) peroxydicarbonate has been studied. The mechanism of decomposition is a simple bond fission, homogeneous first‐order process when the reaction is carried out in the presence of inert gases such as N~2~ or CO. An activation energy of 28.5 kca

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The thermal addition of CF,0sCF3(T 1 to CF2CCl2(E) has been investigated between 49.6 and 69.5"C. The initial pressure of CFJ03CF3 was varied between 7 and 240 torr and that of CF2CC12 between 4 and 600 torr. Four products of formula CF30(E),00CF3, wherej = 1 + 4 are formed. The sum of the products