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Trifluoromethylation of heterocumulenes with trimethyl(trifluoromethyl)silane in the presence of fluoride ions: synthesis of trifluoroacetamides and trifluorothioacetamides from isocyanates and isothiocyanates

✍ Scribed by Nataliya V Kirij; Yurii L Yagupolskii; Nataliya V Petukh; Wieland Tyrra; Dieter Naumann

Book ID
104231812
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
104 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

Trimethyl(trifluoromethyl)silane reacts in the presence of fluoride ions with isocyanates and isothiocyanates under mild conditions to give corresponding trifluoroacetamides and trifluorothioacetamides in high yields.

πŸ“œ SIMILAR VOLUMES

Perfluoroalkylation of heterocumulenes w
Perfluoroalkylation of heterocumulenes with trimethyl(perfluoroalkyl)silanes in the presence of fluoride ions: synthesis of perfluoroalkanesulfinyl amides from N-organylsulfinyl amines
✍ Yurii L. Yagupolskii; Nataliya V. Kirij; Aleksey V. Shevchenko; Wieland Tyrra; D πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 136 KB

Trimethyl(perfluoroalkyl)silanes react in the presence of fluoride ions with N-organylsulfinylamines under mild conditions to give the corresponding perfluoroalkanesulfinyl amides in high yields.