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Perfluoroalkylation of heterocumulenes with trimethyl(perfluoroalkyl)silanes in the presence of fluoride ions: synthesis of perfluoroalkanesulfinyl amides from N-organylsulfinyl amines

โœ Scribed by Yurii L. Yagupolskii; Nataliya V. Kirij; Aleksey V. Shevchenko; Wieland Tyrra; Dieter Naumann

Book ID
104250790
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
136 KB
Volume
43
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Trimethyl(perfluoroalkyl)silanes react in the presence of fluoride ions with N-organylsulfinylamines under mild conditions to give the corresponding perfluoroalkanesulfinyl amides in high yields.

๐Ÿ“œ SIMILAR VOLUMES

Trifluoromethylation of heterocumulenes
Trifluoromethylation of heterocumulenes with trimethyl(trifluoromethyl)silane in the presence of fluoride ions: synthesis of trifluoroacetamides and trifluorothioacetamides from isocyanates and isothiocyanates
โœ Nataliya V Kirij; Yurii L Yagupolskii; Nataliya V Petukh; Wieland Tyrra; Dieter ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 104 KB

Trimethyl(trifluoromethyl)silane reacts in the presence of fluoride ions with isocyanates and isothiocyanates under mild conditions to give corresponding trifluoroacetamides and trifluorothioacetamides in high yields.