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Trifluoroacetyl-Activated Nitrogen−Nitrogen Bond Cleavage of Hydrazines by Samarium(II) Iodide

✍ Scribed by Ding, Hui; Friestad, Gregory K.


Book ID
126952797
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
76 KB
Volume
6
Category
Article
ISSN
1523-7060

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It was established that exclusively high regioselective C O bond cleavage of 7-oxabicyclo[2.2.1]heptane skeletons, which are unique Diels-Alder products of furans, under mild conditions using samarium(II) iodide and samarium powder yields cyclohexanol derivatives or aromatic compounds.