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Trifluoroacetyl-Activated Nitrogen—Nitrogen Bond Cleavage of Hydrazines by Samarium(II) Iodide.

✍ Scribed by Hui Ding; Gregory K. Friestad


Book ID
101954033
Publisher
John Wiley and Sons
Year
2004
Weight
107 KB
Volume
35
Category
Article
ISSN
0931-7597

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✍ Akihiro Yoshida; Hiroaki Takayama 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 104 KB

It was established that exclusively high regioselective C O bond cleavage of 7-oxabicyclo[2.2.1]heptane skeletons, which are unique Diels-Alder products of furans, under mild conditions using samarium(II) iodide and samarium powder yields cyclohexanol derivatives or aromatic compounds.