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Tricyclo[5.3.0.01,6]decan-5-one and tricyclo[5.4.0.01,6]undecan-5-one. Synthesis and selective transformation to spiro and fused bicyclic systems

โœ Scribed by Ruppert, John F.; White, James D.

Book ID
127154607
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
775 KB
Volume
103
Category
Article
ISSN
0002-7863

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Unusual rearrangement of tricyclo[6.3.0.
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โœ Masaki Ue; Hiroshi Tsukahara; Kazuya Kobiro; Kiyomi Kakiuchi; Yoshito Tobe; Yosh ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 173 KB

cis, truns-Tricyclo[ 6.3.0.0 124 ] undecan-B-one (3 rearranged under acidic conditions through unusual pathways to give cis,cis-tricyclo[ 6.3.0.01,5]undecan-I-one (3. The application to the c-methylene derivative of 2 afforded the angularly fused triquinane having an a-methylenecyclopentanone unit.