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Construction of the bicyclo[6.3.0]undecane skeleton via ring opening of tricyclo[6.3.0.01,4]undecan-5-ones

โœ Scribed by Kakiuchi, Kiyomi; Fukunaga, Keisuke; Jimbo, Mamoru; Yamaguchi, Bunji; Tobe, Yoshito


Book ID
118748063
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
575 KB
Volume
57
Category
Article
ISSN
0022-3263

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Unusual rearrangement of tricyclo[6.3.0.
โœ Masaki Ue; Hiroshi Tsukahara; Kazuya Kobiro; Kiyomi Kakiuchi; Yoshito Tobe; Yosh ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 173 KB

cis, truns-Tricyclo[ 6.3.0.0 124 ] undecan-B-one (3 rearranged under acidic conditions through unusual pathways to give cis,cis-tricyclo[ 6.3.0.01,5]undecan-I-one (3. The application to the c-methylene derivative of 2 afforded the angularly fused triquinane having an a-methylenecyclopentanone unit.