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Tricyclo[4.1.0.0]hept-4-ene als Zwischenstufen

✍ Scribed by Priv.-Doz. Dr. Udo H. Brinker; Klaus Gomann; Ruth Zorn


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
222 KB
Volume
95
Category
Article
ISSN
0044-8249

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3. On the other hand, the rearrangement of the tricycle 1 could take place via retro-Diels-Alder reaction or via diradicals as intermediates. The conversion into 3 might be initiated by rupture of the C2-C3 and/or C1-C6 bonds. Hydrogenation (Pt/C, pentane) of 1 affords 4-and 5methyl-2,3-benzobicycl

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