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4,5-Benzotricyclo[4.1.0.01,3]hept-4-en

โœ Scribed by Dr. Udo H. Brinker; Joachim Streu


Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
259 KB
Volume
92
Category
Article
ISSN
0044-8249

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4,5-Benzotricyclo[4.1.0.01,3]hept-4-ene
โœ Dr. Udo H. Brinker; Joachim Streu ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 254 KB
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โœ Priv.-Doz. Dr. Udo H. Brinker; Klaus Gomann; Ruth Zorn ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 231 KB

3. On the other hand, the rearrangement of the tricycle 1 could take place via retro-Diels-Alder reaction or via diradicals as intermediates. The conversion into 3 might be initiated by rupture of the C2-C3 and/or C1-C6 bonds. Hydrogenation (Pt/C, pentane) of 1 affords 4-and 5methyl-2,3-benzobicycl