The structure of the strained tricyclic hydrocarbon tricyclo [ 4.2.0.0'~~ I octane was determined by a combination of 1D and 2D NMR involving both proton and carbon signals. The stereochemistry of the molecule was determined by NOE difference spectroscopy. The assigned structure corresponds to the t
โฆ LIBER โฆ
Tricyclo[3.2.1.01,5]octane
โ Scribed by Kenneth B. Wiberg; George J. Burgmaier
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 121 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
We have recently reported that 8-oxatricyclo[ 3. 2. 1. 0" 5]octane, in which the normal
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Wir beschreiben eine allgemeine Synthese der fruher schwer zuglnglichen Azirine (Azacyclopropene) (3). An eine stereospezifische JN3-Anlagerung a n Olefine schlie8t sich eine HJ-Eliminierung zu Vinylaziden (2) an, die photolytisch in die I-Azirine (3) iibergefiihrt werden konnen. Auf diese Weise sin