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NMR examination of tricyclo[4.2.0.01,3]octane

✍ Scribed by William B. Smith; Udo H. Brinker

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 230 KB
Volume: 29
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260290510

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✦ Synopsis

The structure of the strained tricyclic hydrocarbon tricyclo [ 4.2.0.0'~~ I octane was determined by a combination of 1D and 2D NMR involving both proton and carbon signals. The stereochemistry of the molecule was determined by NOE difference spectroscopy. The assigned structure corresponds to the thermodynamically more stable fruns form as ascertained by molecular mechanics calculations.

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