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Tri­carbonyl­(η6-N,N-di­methyl­aniline)­chromium(0)

✍ Scribed by Zeller, Matthias ;Hunter, Allen D.


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
479 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, [Cr{(C 6 H 5 N(CH 3 ) 2 }(CO) 3 ], exhibits the three-legged piano-stool structure expected for a tricarbonylmetal with an 6 -coordinated arene. The arene moiety is distorted with the amino functional group bent away from the chromium atom.


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The title compound, [Cr(C 6 H 5 CF 3 )(CO) 3 ], exhibits the threelegged piano-stool structure expected for a tricarbonylmetal complex with an 6 -coordinated arene. The tri¯uoromethyl functional group is tilted towards the Cr(CO) 3 center.

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