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Tri­carbonyl(η6-4-fluoro­aniline)­chromium

✍ Scribed by Zeller, Matthias ;Hunter, Allen D. ;Regula, Jody L. ;Szalay, Paul S.


Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
299 KB
Volume
59
Category
Article
ISSN
1600-5368

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Single-crystal X-ray study T = 100 K Mean '(C±C) = 0.002 A Ê R factor = 0.025 wR factor = 0.070 Data-to-parameter ratio = 14.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The title compound, [Cr(C 6 H 5 CF 3 )(CO) 3 ], exhibits the threelegged piano-stool structure expected for a tricarbonylmetal complex with an 6 -coordinated arene. The tri¯uoromethyl functional group is tilted towards the Cr(CO) 3 center.

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The title compound, [Cr{(C 6 H 5 N(CH 3 ) 2 }(CO) 3 ], exhibits the three-legged piano-stool structure expected for a tricarbonylmetal with an 6 -coordinated arene. The arene moiety is distorted with the amino functional group bent away from the chromium atom.

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Single-crystal X-ray study T = 100 K Mean '(C±C) = 0.003 A Ê R factor = 0.025 wR factor = 0.069 Data-to-parameter ratio = 16.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.