R-XC1, + 3 C(SilLle,), 7 R-X 3 LlCl v c1' -CI,C(SiMe,)> C(SiMe3)2 l a -c 2 3 a -c 4 c (20.6 g, 0.09 mol) cooled to -110°C. The mixture was stirred for 3 h, then treated with a solution of l c (6.57 g, 0.03 mol) in T H F (10 mL), and allowed to warm to -15°C. The solvents were then removed and the m
✦ LIBER ✦
Tricarbonyl(1,3-diphosphaallyl)cobalt, ein Phosphoranalogon von (η3-Allyl)tricarbonylcobalt
✍ Scribed by Prof. Dr. Rolf Appel; Winfried Schuhn; Dr. Falk Knoch
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 203 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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Eingegangen am 29. Oktober 1981 2,2',3,3'-TetraphenyIbi-2-cyclopropen-l-yl (1) und Fe,(CO), reagieren bei Raumtemperatur unter Bildung von (4 -7-~4-2,3,5,7-Tetraphenyl-2,4,6-cycloheptatrien-l-on)Fe(CO)3 (3). Diese unerwartete Umlagerung eines Bicyclopropenyl-Derivats in einen Tropon-Komplex verlauft