Triazolinyl radicals – new additives for controlled radical polymerization
✍ Scribed by Marco Steenbock; Markus Klapper; Klaus Müllen
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 641 KB
- Volume
- 199
- Category
- Article
- ISSN
- 1022-1352
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## Abstract Well‐controlled radical polymerization of methyl methacrylate can be achieved by __in situ__ photochemical generation of copper (I) complex from air‐stable copper (II) species without using any reducing agent at room temperature. The living character of this polymerization was confirmed
We describe the basic kinetic features of "living" polymerizations controlled and regulated by persistent radicals or related species and by reversible atom transfer. In these systems a special kinetic phenomenon operates-the Persistent Radical Ef-fect. It is also known from selective organic synthe