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Photoinduced Controlled Radical Polymerization

โœ Scribed by Mehmet Atilla Tasdelen; Mustafa Uygun; Yusuf Yagci

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
237 KB
Volume
32
Category
Article
ISSN
1022-1336

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โœฆ Synopsis

Abstract

Wellโ€controlled radical polymerization of methyl methacrylate can be achieved by in situ photochemical generation of copper (I) complex from airโ€stable copper (II) species without using any reducing agent at room temperature. The living character of this polymerization was confirmed by both the linear tendency of molecular weight evolution with conversion and a chain extension experiment.

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๐Ÿ“œ SIMILAR VOLUMES

Photoinduced Controlled Radical Polymeri
Photoinduced Controlled Radical Polymerization in Methanol
โœ Mehmet Atilla Tasdelen; Mustafa Uygun; Yusuf Yagci ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 382 KB

## Abstract Photoinduced CRP of methyl methacrylate initiated by in situ generation of copper (I) complex from higher oxidation state species in methanol was investigated. The polymerizations proceeded in a wellโ€controlled manner under UV light at room temperature as evidenced by kinetic and chain