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Triazabicyclodecene: A Simple Bifunctional Organocatalyst for Acyl Transfer and Ring-Opening Polymerization of Cyclic Esters

✍ Scribed by Pratt, Russell C.; Lohmeijer, Bas G. G.; Long, David A.; Waymouth, Robert M.; Hedrick, James L.


Book ID
119978834
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
100 KB
Volume
128
Category
Article
ISSN
0002-7863

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Zn(OAc) 2 β€’2H 2 O is found to be an effective bulk polymerization catalyst for the ring-opening polymerization of rac-lactide, l-lactide, -caprolactone and ␦-valerolactone. The propensity of polymerizations can be enhanced by performing them in the presence of appropriate amounts of different alcoho