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Synthesis and Structure of a Molecular Barium Aminebis(phenolate) and Its Application as an Initiator for Ring-Opening Polymerization of Cyclic Esters

✍ Scribed by Davidson, Matthew G.; O'Hara, Charles T.; Jones, Matthew D.; Keir, Callum G.; Mahon, Mary F.; Kociok-Köhn, Gabriele


Book ID
127346188
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
74 KB
Volume
46
Category
Article
ISSN
0020-1669

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A spiro orthoester having an ester moiety, 2-acetoxymethyl-1,4,6trioxaspiro[4.6]undecane (4) was synthesized, and its cationic polymerization and depolymerization of the obtained polymer (5) were carried out. The monomer 4 underwent cationic polymerization with a cationic catalyst to afford the corr