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Tri­aqua­formatobis(4-formyl-2-methoxy­phenolato)­gadolinium(III)

✍ Scribed by Gao, Shan ;Huo, Li-Hua ;Zhang, Xian-Fa ;Zhao, Hui

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
312 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title complex, [Gd(L) 2 (CHO 2 )(H 2 O) 3 ] (L À = 4-formyl-2-methoxyphenolate anion, C 8 H 7 O 3 ), the Gd III ion occupies a site with mirror symmetry and assumes a bicapped triangular prismatic coordination environment de®ned by four O atoms from two L À ligands, three O atoms from three coordinated water molecules and one O atom from a formate group. The formate group and one water molecule lie on a mirror plane. A three-dimensional network is formed by OÐHÁ Á ÁO hydrogen-bond interactions.

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