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Triaqua­(2,2′-bipyridine)(4-sulfonatobenzoato)manganese(II) monohydrate containing seven-coordinate manganese

✍ Scribed by Zhang, Li-Ping ;Zhu, Long-Guan

Book ID
104484120
Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
187 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The mononuclear title complex, [Mn(C 7 H 4 O 5 S)(C 10 H 8 N 2 )-(H 2 O) 3 ]ÁH 2 O, was obtained from the hydrothermal reaction of manganese acetate, potassium hydrogen 4-sulfonatobenzoate and 2,2 0 -bipyridine. The geometry of the seven-coordinate Mn II atom is a monocapped trigonal prismatic. Each 4sulfonatobenzoate anion chelates to the metal atom via its carboxyl O atoms. The crystal structure is stabilized by a threedimensional O-HÁ Á ÁO hydrogen-bond network.

📜 SIMILAR VOLUMES

Triaqua[2-(4-carboxylatophenoxy)propiona
Triaqua[2-(4-carboxylatophenoxy)propionato-κO](1,10-phenanthroline-κ2N,N′)manganese(II) monohydrate
✍ Xiao, Ying-Hui ;Kong, Li-Li ;Gao, Shan 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 447 KB

The zwitterionic title compound, [Mn(C 10 H 8 O 5 )(C 12 H 8 N 2 )-(H 2 O) 3 ]ÁH 2 O, has the Mn atom in an octahedral geometry that comprises the O atom of the 2-(4-carboxylatophenoxy)propionate group, two N atoms of the 1,10-phenanthroline ligand and three water molecules. Extensive hydrogenbondin