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Triaqua­(2,2′-bipyridine)(2-sulfonatobenzoato)cobalt(II)

✍ Scribed by Xiao, Hong-Ping


Book ID
104486126
Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
234 KB
Volume
62
Category
Article
ISSN
1600-5368

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Triaqua­(2,2′-bipyridine)(4-sulfonatoben
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The mononuclear title complex, [Mn(C 7 H 4 O 5 S)(C 10 H 8 N 2 )-(H 2 O) 3 ]ÁH 2 O, was obtained from the hydrothermal reaction of manganese acetate, potassium hydrogen 4-sulfonatobenzoate and 2,2 0 -bipyridine. The geometry of the seven-coordinate Mn II atom is a monocapped trigonal prismatic. Each

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In the title polymeric complex, [Pb(C 7 H 4 O 5 S)(C 10 H 8 N 2 )-(H 2 O)] n , each Pb II atom has a seven-coordinate geometry. The 3-sulfonatobenzoate ligand acts as a 3 -bridging linker, generating a one-dimensional ladder. The packing is further stabilized by an O-HÁ Á ÁO hydrogen-bonding network