Trapping of reactive intermediates in dienone photochemistry by amines

✍ Scribed by Angelo C. Brisimitzakis; David I. Schuster

• Book ID: 104219655
• Publisher: Elsevier Science
• Year: 1982
• Tongue: French
• Weight: 200 KB
• Volume: 23
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)85646-4

✦ Synopsis

Irradiation of 4-methyl-4-trichloromethyl-2,5-cyclohexadienones in amine solvents leads tn the formation of the corresponding dichloromethyl cyclohexadienones by a process involving electron transfer from the amines tn zwitterion intermediates.