Irradiation of 4-methyl-4-trichloromethyl-2,5-cyclohexadienones in amine solvents leads tn the formation of the corresponding dichloromethyl cyclohexadienones by a process involving electron transfer from the amines tn zwitterion intermediates.
โฆ LIBER โฆ
Highly reactive intermediates in photochemistry of chlorophyll
โ Scribed by Lobanov, A. V. ;Komissarov, G. G.
- Book ID
- 120802793
- Publisher
- Biophysical Society of Japan
- Year
- 2013
- Tongue
- English
- Weight
- 149 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1349-2942
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The synthesis of di(a-thieny1)hexamethyltrisilane (1) is described. In the photolysis of 1 with cyclohexene and methanol, an apparent radical reaction occurred. We suspect that the sulfur atom of the thienyl group strongly stabilizes an initially formed silyl radical. This idea was supported both by