Trapping of hydrated electrons by cetyl pyridinium chloride micelles
✍ Scribed by M. Grätzel; J.K. Thomas; L.K. Patterson
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 585 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Using a surfirctant (c&y1 pyridinium chIoide) whose head gro~~p itse~~ap~~~y reacts with e& the safe ofhydrated electron trapping in the positively charged micelie surface has been measure& Fiom the h&h rate constant obtained (~5 X lOI M-l s-l) and its very marked dependence'on ionic strength, doubie layer theory may be evoked to explain '.
📜 SIMILAR VOLUMES
Results of adiabatic molecular dynamics simulations for a hydrated electron and the aqueous chloride anion are reported. A novel technical feature is the efficient representation of solute electronic wavefunctions in terms of floating spherical Gaussian orbitals. The simulations account for the coup
A method is described for the indirect determination of trace and ultratrace concentrations of hexadecyltrimethylammonium bromide (HThlAB) and ce&l pyridinium chloride (CPC) in industrial and consumer products b!. adsorpti\:e voltammetrj.. The determination of HTMAB at the trace concentration was ac