Trapping {BW12}2 tungstoborate: synthesis and crystal structure of hybrid [{(H2BW12O42)2O}{Mo6O6S6(OH)4(H2O)2}]14− anion
✍ Scribed by Korenev, V. S.; Abramov, P. A.; Vicent, C.; Mainichev, D. A.; Floquet, S.; Cadot, E.; Sokolov, M. N.; Fedin, V. P.
- Book ID
- 115313468
- Publisher
- Royal Society of Chemistry
- Year
- 2012
- Tongue
- English
- Weight
- 759 KB
- Volume
- 41
- Category
- Article
- ISSN
- 1477-9226
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## Abstract Two 2D Anderson polyoxomolybdate‐based compounds, [{Ni(H~2~O)~4~}~2~{Ni(OH)~6~Mo~6~O~18~}]·4H~2~O (1) and [Ni(H~2~O)~6~][Ag~2~{Ni(OH)~6~Mo~6~O~18~}]·8H~2~O (2), were synthesized and characterized by elemental analysis, IR spectroscopy, SEM, and single‐crystal XRD. Their thermal behavior
A new compound containing polyoxovanadoborate anion was synthesized and characterized by single-crystal X-ray diffraction analysis. A water molecule at the center of the anion was precisely determined. The crystals of the new compound belong to the monoclinic system, space group P2 1 /n with a=1.350