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Transposition d'oxy-cope a temperature ambiante catalysee par le dichlorure de palladium-bisbenzonitrile.

โœ Scribed by Norbert Bluthe; Max Malacria; Jacques Gore


Book ID
104220149
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
228 KB
Volume
24
Category
Article
ISSN
0040-4039

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Reaction des hexadiene-1,5 ols-3 avec le
โœ Norbert Bluthe; Max Malacria; Jacques Gore ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 226 KB

Tertiary 1,5-hexadien-3-01s 1 are transformed to A-ethylene ketones 2 in yield by treatment with one equivalent of mercuric trifluoroacetate and subsequent ration using sodium borohydride (Scheme 1, Table ). ## 35-15 % demercu- La transposition d'Oxy-Cope (schema 1) a fait l'objet de nombreux tra