✦ LIBER ✦
Reaction des hexadiene-1,5 ols-3 avec le trifluoroacetate mercurique ; transposition d'oxy-cope a temperature ambiante.
✍ Scribed by Norbert Bluthe; Max Malacria; Jacques Gore
- Book ID
- 104221988
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 226 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Tertiary 1,5-hexadien-3-01s 1 are transformed to A-ethylene ketones 2 in yield by treatment with one equivalent of mercuric trifluoroacetate and subsequent ration using sodium borohydride (Scheme 1, Table ).
35-15 % demercu-
La transposition d'Oxy-Cope (schema 1) a fait l'objet de nombreux travaux (11, tant sur le plan de son mecanisme, que sur celui de son utilisation en synthese.