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Transmission electron microscopy study of amorphization and precipitation in Ni+-implanted aluminium

โœ Scribed by M.F Denanot; O Popoola; P Moine


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
708 KB
Volume
115
Category
Article
ISSN
0921-5093

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โœฆ Synopsis


Implantation of nickel ions into pure aluminium is found to produce either amorphization or precipitation of a cubic phase not predicted by the Al-Ni phase diagram. Under low ion current (I<<. 1 /uA cm -2) and for fluences between 8xlO m Ni + cm 2 and 2 x 1017 Ni + cm-2 an amorphous phase forms. Under high current (1=20 IzA cm -2) and for the same fluences a new face-centred cubic (f.c.c.) Al~sNit5 precipitate phase is formed in epitaxy with a supersaturated Al9sNi 5 solid solution. The epitaxial relationship between the precipitates p and the solid solution matrix m is (O01)p//(OO1)m planes, and [040]p//[240]m directions in the planes. The large lattice misfit between the precipitates and the matrix is accommodated by twinning and a tetragonal distortion of the precipitates.


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โœ H.-I. Su; K. Heinemann; H. Poppa; M. Boudart ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 837 KB

Palladium clusters, \(10-30 \mathrm{~nm}\) in size, were grown in UHV on amorphous carbon in a transmission electron microscope (TEM). The Pd catalyzed oxidation of carbon was then followed in situ in the TEM between 720 and \(800 \mathrm{~K}\) at a pressure \(p\) of \(\mathrm{O}_{2}\) with \(\left.