Transmembrane electron transfer as catalyzed by manganese porphyrin derivatives
β Scribed by M. Nango; K. Tsuda
- Book ID
- 103956292
- Publisher
- Elsevier Science
- Year
- 1991
- Weight
- 56 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0923-1137
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π SIMILAR VOLUMES
Equilenin acetate and dihydroequilenin acetate were oxidized with iodosobenzene and a rhodium(III) porphyrin catalyst. The selectivity of the reactions differs from that with the corresponding Mn(III) catalyst, or from that of free radical chain oxidation.
## Abstract Poly(Ξ³βmethyl Lβglutamate) (PMLG) membrane containing manganese tetrakis(pentafluorophenyl)porphyrinSystematic name: Tetrakis(pentafluorophenyl)porphyrinatomanganese. (MnPFPP) has been studied for the transmembrane redox reaction between dithionite and ferricyanide in separated solutio