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Regioselective oxidations of equilenin derivatives catalyzed by a rhodium(III) porphyrin complex—contrast with the manganese(III) porphyrin

✍ Scribed by Jerry Yang; Ronald Breslow

Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 90 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)01402-7

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✦ Synopsis

Equilenin acetate and dihydroequilenin acetate were oxidized with iodosobenzene and a rhodium(III) porphyrin catalyst. The selectivity of the reactions differs from that with the corresponding Mn(III) catalyst, or from that of free radical chain oxidation.

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