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Translational energy release and stereochemistry of steroids 6—Contribution of the 18- and 19-methyl groups to the translational energy release for the angular methyl loss in unsaturated steroids

✍ Scribed by Z. V. I. Zaretskii; Z. Kustanovich; E. E. Kingston; J. H. Beynon; R. Lauber; U. P. Schlunegger; Carl Djerassi

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
256 KB
Volume
20
Category
Article
ISSN
1076-5174

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Translational energy release and stereoc
Translational energy release and stereochemistry of steroids. VII—the loss of angular methyl groups after the dehydration of molecular ions of cholesterol and related C(5)-unsaturated 3β-hydroxy steroids
✍ Z. V. I. Zaretskii; Z. Kustanovich; E. E. Kingston; J. H. Beynon; Carl Djerassi; 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 741 KB

The translational energy, T, released during the loss of the angular 18and 19-methyl groups both from metastable molecular ions and metastable [M -H,O]" and [M -2 H,O]+' ions, in C(5)-unsaturated monoand di-hydroxy steroids, as well as in their 19-nor and deuterated analogues bearing the label in th