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Translational energy release and stereochemistry of steroids. VIII-The mechanism of the elimination of water from metastable ions in epimeric 3-hydroxy steroids of the 5α-series

✍ Scribed by Z. V. I. Zaretskii; J. M. Curtis; A. G. Brenton; J. H. Beynon; Carl Djerassi

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
616 KB
Volume
23
Category
Article
ISSN
1076-5174

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The translational energy, T, released during the loss of the angular 18and 19-methyl groups both from metastable molecular ions and metastable [M -H,O]" and [M -2 H,O]+' ions, in C(5)-unsaturated monoand di-hydroxy steroids, as well as in their 19-nor and deuterated analogues bearing the label in th