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Transition structures of aldol reactions

โœ Scribed by Li, Yi.; Paddon-Row, Michael N.; Houk, K. N.


Book ID
115461623
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
616 KB
Volume
110
Category
Article
ISSN
0002-7863

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Aldol reaction of trichlorotitanium enol
โœ Eiichi Nakamura; Isao Kuwajima ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 257 KB

The trichlorotitanium enolates generally undergo an erythro \_\_\_\_\_ selective aldol reaction except one case which gives a threo aldol. A new form of the boat transition state has been proposed. The chair transition state (TS) hypothesis has been the central dogma in aldol chemistry. 1 Here we