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Transition structures for additions of lithium hydride and methyllithium to ethylene and acetylene

โœ Scribed by Houk, Kendall N.; Rondan, Nelson G.; Schleyer, Paul v. R.; Kaufmann, E.; Clark, Timothy


Book ID
127046084
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
349 KB
Volume
107
Category
Article
ISSN
0002-7863

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Kinetics of gas-phase addition reactions
โœ Pauline M. Holt; J. Alistair Kerr ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 643 KB

The reactions have been studied by a mass-balance method involving the photolysis of small amounts of biacetyl in the presence of a large excess of isobutane containing a small proportion of the unsaturated substrate. The following Arrhenius parameters have been derived: Temperature Reaction E log A