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Transition structure for the reaction of a carbenoid, (fluoromethyl)lithium, with ethylene

โœ Scribed by Mareda, Jiri; Rondan, Nelson G.; Houk, K. N.; Clark, Timothy; Schleyer, Paul V. R.


Book ID
127039489
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
366 KB
Volume
105
Category
Article
ISSN
0002-7863

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โœ E.J Corey; Francis J Hannon ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 269 KB

A transition state assembly is proposed for the l&addition of lithium dimethylcuprate to a$unsaturated ketones which provides general agreement with experimental observations of high stereoselectivity for substrates such as chiral al-substituted a$-enones, Ssubstituted 2-cyclohexenones, medium ring