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Transition structure for the epoxidation of alkenes with peroxy acids. A theoretical study

โœ Scribed by Bach, Robert D.; Owensby, Amy L.; Gonzalez, Carlos; Schlegel, H. Bernard; McDouall, Joseph J. W.

Book ID
117989942
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
334 KB
Volume
113
Category
Article
ISSN
0002-7863

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An analysis of the diastereomeric transi
An analysis of the diastereomeric transition state interactions for stereoselective epoxidation of acyclic allylic alcohols with peroxy-acids
โœ Acharan S. Narula ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 234 KB

Consideration of the magnitude of A (1,2) and A(lj3) -strain in the transition state of the epoxidation of acyclic allylic alcohols, has powerful predictive value. Among the reactions1 which are useful for controlling stereo-, regio-, and chemoselectivity in acyclic systems, epoxidation of acyclic