✦ LIBER ✦

An analysis of the diastereomeric transition state interactions for stereoselective epoxidation of acyclic allylic alcohols with peroxy-acids

✍ Scribed by Acharan S. Narula

Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 234 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)92893-x

No coin nor oath required. For personal study only.

✦ Synopsis

Consideration of the magnitude of A (1,2) and A(lj3) -strain in the transition state of the epoxidation of acyclic allylic alcohols, has powerful predictive value.

Among the reactions1 which are useful for controlling stereo-, regio-, and chemoselectivity in acyclic systems, epoxidation of acyclic allylic alcohols, using either

📜 SIMILAR VOLUMES

An analysis of the diastereomeric transi

An analysis of the diastereomeric transition state interactions for the kinetic deprotonation of acyclic carbonyl derivatives with lithium diisopropylamide

✍ Acharan S Narula 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 282 KB

Consideration of A (1,2) and A(1'3) -strain in the transition states for the deprotonation of carbonyl compounds using LDA as a base has powerful predictive value.

Stereoselective introduction of chiral c

Stereoselective introduction of chiral centres in acyclic precursors : a probe into the transition state of m-chloroperbenzoic (m-CPBA) acid epoxidation of acyclic allylic alcohols and its synthetic implications

✍ Acharan S. Narula 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 244 KB

ChemInform Abstract: Competition Between

ChemInform Abstract: Competition Between Peroxy Acid Oxygens as Hydrogen Bond Acceptors in B3LYP Transition Structures for Epoxidations of Allylic Alcohols with Peroxyformic Acid.

✍ Mauro Freccero; Remo Gandolfi; Mirko Sarzi-Amade; Augusto Rastelli 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 26 KB 👁 1 views

Stereoselective introduction of chiral c

Stereoselective introduction of chiral centres in acylic precursors: a probe into the transition state for V5+-catalyzed t-butylhydroperoxide (TBHP) epoxidation of acyclic allylic alcohols and its synthetic implications.

✍ Acharan S. Narula 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 231 KB