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An analysis of the diastereomeric transition state interactions for the kinetic deprotonation of acyclic carbonyl derivatives with lithium diisopropylamide

✍ Scribed by Acharan S Narula

Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 282 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)82081-5

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✦ Synopsis

Consideration of A (1,2) and A(1'3) -strain in the transition states for the deprotonation of carbonyl compounds using LDA as a base has powerful predictive value.

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An analysis of the diastereomeric transition state interactions for stereoselective epoxidation of acyclic allylic alcohols with peroxy-acids

✍ Acharan S. Narula 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 234 KB

Consideration of the magnitude of A (1,2) and A(lj3) -strain in the transition state of the epoxidation of acyclic allylic alcohols, has powerful predictive value. Among the reactions1 which are useful for controlling stereo-, regio-, and chemoselectivity in acyclic systems, epoxidation of acyclic