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Transition States and Origins of Stereoselectivity of Epoxidations by Oxaziridinium Salts

โœ Scribed by Washington, Ilyas; Houk, K. N.


Book ID
125505650
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
82 KB
Volume
122
Category
Article
ISSN
0002-7863

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Consideration of the magnitude of A (1,2) and A(lj3) -strain in the transition state of the epoxidation of acyclic allylic alcohols, has powerful predictive value. Among the reactions1 which are useful for controlling stereo-, regio-, and chemoselectivity in acyclic systems, epoxidation of acyclic