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Transition State Spectroscopy of the Photoinduced Ca + CH 3 F Reaction. 1. A Cluster Isolated Chemical Reaction Study

✍ Scribed by Gaveau, M.-A.; Gloaguen, E.; Fournier, P.-R.; Mestdagh, J.-M.

Book ID
126136265
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
84 KB
Volume
109
Category
Article
ISSN
1089-5639

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## Abstract The rate coefficient for NH~2~ + CH~4~ β†’ NH~3~ + CH~3~ (R1) has been measured in a shock tube in the temperature range 1591–2084 K using FM spectroscopy to monitor NH~2~ radicals. The measurements are combined with a calculation of the potential energy surface and canonical transition s