A METHOD FOR THE STUDY OF CHLORINE ATOM REACTIONS. THE REACTION Cl + CH 4 → CH 3 + HCl
✍ Scribed by Pritchard, H. O.; Pyke, J. B.; Trotman-Dickenson, A. F.
- Book ID
- 127372334
- Publisher
- American Chemical Society
- Year
- 1954
- Tongue
- English
- Weight
- 253 KB
- Volume
- 76
- Category
- Article
- ISSN
- 0002-7863
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## Abstract A direct dynamics method is employed to study the kinetics of the multiple channel reaction CH~3~OCl + Cl. The potential energy surface (PES) information is explored from __ab initio__ calculations. Two reaction channels, Cl‐ and H‐abstractions, have been identified. The optimized geome
The rate constant for the reaction C1+ CH, 1 , CH3 + HCl has been determined over the temperature range of 200"-500"K using a discharge flow system with resonance fluorescence detection of atomic chlorine under conditions of large excess CH4. For 300" > 7' > 200°K the data are best fitted to the exp